Her husband gets veto'd from the running, so the wife goes in as a candidate. Sorry, the optics on that alone looks really bad for neutral voters. She wasn't the movements first choice of leader, it was her husband, and it's reasonable to think that even if she's now in the running, she's overtly a puppet for other interests that are obscured. Add in a seemingly staunch adherence to what appears to be the tired old left-leaning minority demographic approach -- where they target different minority groups with perks/benefits/funding promises that benefit those minorities exclusively, while ignoring and throwing shit at the majority interests of the voters -- isn't a winning strategy overall. One of the keys to the appeal of a leader like Jack Layton, was that he appealed to the interests of most people.
Just because Canadians rejected PP last time, doesn't mean they want to go to the complete opposite side of that spectrum. Electing this lady would likely end as tragically as the Green party electing Annamie Paul.