In the context of using this to punch down at a non-profit I can see some reasons.
OP is not a state level target, the consequences of them getting hacked is they home to make a police report and close some bank accounts. The non profit is not concerned with OP being targeted by the US government, their goal is to provide serviceable computers to needy people.
It's surface level relevant to the zero waste conversation, but only if you don't value anything but the old outdated PC. Older processors like this have such bad processing efficiency that the energy savings alone would pay for a new SBC in a year, presuming heavy use. Then there are the logistical costs and labor of managing that supply of old equipment. A few generations of architecture mean that peripheral and add-in cards are not available or wouldn't work. The dwindling stock of donor equipment means that the resources to even assemble a working order PC will be higher than newer equipment.
There's the same arguments to be had about older refrigeration equipment. Yes, it's probably better to keep it serviced, but as soon as a big problem comes along a newer more efficient unit should be installed.