Stockfish and RubiChess agree that Qb3 is the best move. RubiChess (blue arrows) is only considering attacking while Stockfish (green arrows) has Kh2 and Kh1 in its top moves (+6.25 and +6.99 versus +6.57 for Qb3).

I think the general idea is that the black rook on e8 implies the strategy to get that rook to e1. The move Kh2 avoids that check.
I don't really find that argument convincing myself. White is clearly ahead so just increase the pressure and black will probably have no time for a counterattack anyways.