In terms of pedaling, it doesn't matter. The same ratio between teeth in the front divided by teeth in the back will feel exactly the same. The only rule here is that you are aiming to keep the chain in a somewhat straight line. Supposing you have two chainrings in the front: Never go small-small or large-large, as that would put strain on the components. For a 2x11, for example, usually all gears are safe except for 1-11 or 2-1, if that makes sense.
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