Is it shown that there are significant performance benefits to installing daemons and utilities à la carte?
No, not really.
Is it because arch users are enthusiasts that enjoy trying to optimize their system?
This is IMHO the most important aspect. The thing they're trying to optimize isn't performance, though, it's more "usability", i.e. making the system work for you. When you get down to it and understand all the components of the OS, and all the moving parts within, you can set it up however you prefer and then combine them in novel ways to solve your tasks more quickly.