I mean, this is essentially all hiring processes.
The way to get actually good employees is to be the sort of place that actual good employees want to work for. Good pay, good work-life balance, good managers and company culture, work that is enjoyable and meaningful. Then, you hire through social networks. The founders start off as people who meet through informal social networks. They hire their friends. And then they ask their friends for further recommendations. The best way to know if someone is a good hire is if you have actually worked with them before. And at this point, the interview is really just hanging out, shaking hands, and having lunch before you sign some paperwork.