100% efficiency isnt that good when heat pumps can comfortably push 400-500%, and its not always the full story. An electric heater that converted the electricity to heat, but doesnt disperse it around the room effectively is 100% efficient, but still kinda useless.
Insulation is a big win though. Honeycomb blinds are not terribly expensive, but can do a fantastic job of insulating large windows. You can get them made to size via aliexpress, and its surprisingly cheap.