I’m seeing “PWRSW1” in the cluster to the left.
It is possible to deduce which header is the power switch.
Do you have a multimeter and do you know how to use it?
You want to start by figuring out which pins are GND. Ultimately, you’re looking for a 3.3V signal that is always on.
Connect your power button to a pair of pins that correspond to 3.3V and GND. Pressing the power button pulls that 3.3V signal low, which tells the embedded controller that it’s time to boot up.
If you still have the case, you can also use the connector to make the same determination. With a multimeter set to continuity mode and each probe connected to the right pin, pressing the power button will result in a ‘beep’