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Commander keen
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Wingnuts
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Burn:Cycle
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Myst
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Duke Nukem (the first one but also 3D)
Wingnuts was a dumb fmv 'dog fighting' game, but when you beat it you could play it again with silly dialogue. I also remember when setting up the sound card the test audio was a guy saying 'ah veiners, just ze vay I like zem!' In a bad German accent.
Burn:Cycle was an fmv adventure game that I adored, it also came with a sound track cd and a little packet of leaflets based on in game stuff that was really cool. I still listen to the ost on occasion