You would think, but I believe the law(s) require verification of a photo ID. I haven't looked too closely into the UK one, but the way the laws are written for a couple of the US states a credit card doesn't meet the requirements. There's also the fact that many of the preview images and videos for porn games on Steam show nudity and/or sex and you can access those without needing to purchase the game (just the birthday question to "verify" your age).
Edit: also steam gift cards are a thing, so you can purchase without using a credit card technically.