From my experience, no, it didn't make my microwave small smell. When I used to use my microwave for this, I would run it low & slow. Usually 50% power for a few minutes on somewhat larger desiccant bags. Then I would open up the microwave, let all the steam out and let the bags cool and run it again, rinse and repeat until I no longer saw/felt any steam when I opened the door. I eventually started doing enough 3D printing to invest in a dedicated device, especially since I didn't ever want to dry filament in a microwave. I ended up getting a food dehydrator that can get up to 90°C and it works great for desiccant and filament. I also switched to the pink/blue moisture indicating desiccant beads that don't come in a bag.
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