Death Note and Code Geass are some of the best psychological thrillers.
Cowboy Bebop is an all time great.
Seven Deadly Sins is fun and Four Knights of the Apocalypse is a good sequel.
Bojack Horseman and F is for Family are good western adult animation.
Violet Evergarden is a good romantic/emotional show.
Frieren: Beyond Journey's End and Dungeon Meshi/Delicious in Dungeon are good shows in somewhat the same genre as vox Machina.
RWBY is worth watching at least through season 3, the creator died during the third seasons and the later stuff isn't quite as good.