I think I read somewhere that part of the motivation is that they won't need a runtime to be installed to use it, but Go could fill that role as well of course.
But I think you said it yourself:
I know this is blasphemy, but why not Go? Why Rust? I love writing Rust CLIs
I guess they also prefer Rust to Go. I'd choose Rust over go for a CLI any day. Why do you say Rust wouldn't be good in an "industrial setting"? I use Rust professionally and I don't see any problems in that setting.