Deer do not avoid orange camo, which is why people know it works.
Deer do not avoid cars. Or people drinking in their backyards while kids scream and play with each other.
Again, if orange were some magic anti-deer color, you would just wear a solid orange bunny suit like you were about to go out into the desert and have some fun with Malcolm's Dad.
Also: Again, if any of this bullshit were necessary to "sneak up on the deer" then this continent would have been a giant graveyard as everyone starved because they just didn't have enough camo and dye. Or, I guess, giant metal boxes with bright lights and loud noise makers?
The reality is that deer are SUPER easy to kill (especially with a high powered rifle...). All of this "We have analyzed the eyes and psychology of deer and figured out a great excuse to stop shooting each other, err, I mean, to sneak up on the deer like, get your lotion ready, Carlos Hathcock!!! No, we don't care about Pegahmagabow."
Maybe I am just an old but I remember all the sitcoms where they would have a "hunting episode" and the goober of the group would be wearing all camo and get made fun of. Hell, I want to say there was an episode of Frasier where they go to the cabin and Niles shows up after getting fleeced by a local shop and... he looked a lot like the modern day cosplayer-err, hunter. Not to mention having grown up in the kind of town where Real Men drive a few hours away during deer season to prove they are Men by killing a few deer and talking about how difficult it was.