Passkeys officially have TPM support: https://www.w3.org/TR/webauthn-2/#sctn-tpm-attestation Let's Encrypt doesn't require a TPM. Passkeys can apparently require an actual closed-up DRM anti user hardware component to sign what you're doing.
While Let's Encrypt requires an external party for signing, 1. it's not something the average citizen needs or uses a lot, unlike potentially passkeys, 2. there is no variant of it that works via special DRM hardware that they try to establish everyone as having.
Also, Let's Encrypt is a non-profit while the common Passkey server-side storage vendors don't seem to be.
Anyway, that's just my opinion.
