Bottles and lutris mostly serve the same purpose. heroic might be easier so you can use umu for having a more unified experience with wine and proton but I haven't gotten around to playing with that yet.
I've never used winboat but it seams like a lot of... winbloat...
I would personally just use protontricks to install any needed sotware to the games own prefix but I'm pretty sure lutris, bottles, and heroic can all do this while making a clickable launch button for it, while starting the mod loaders my way requires manual intervention every time.
If you haven't already, check out linux vr adventures: https://lvra.gitlab.io/ I don't know anything about psvr but it might work with monado. i have the facebook shit mask so I use wivrn.