There's definitely queuing depending on the time of day, but most of the stations on the arterial roads seem to be able to manage their tanks. Part of the reason I think queues aren't too bad is that if you have, say, 10 stations, a person is mostly just filling up then paying, so the stations don't have a lot of downtime, and flow rate is not an issue.
With Electric, you'd only be able to have enough stations to match the electric flow rate, so let's say you have a megawatt coming in and 100kW chargers, you'd be able to do 10 at full speed, and you'd probably overprovision by 2 or something, so maybe 20 chargers because not all cars at all stages will charge at that speed, and a hot day might change things etc. Each of these is taking like 20 minutes nominally but that's enough for some snacks and a toilet break, not to mention some people would want to charge to 100%, so people would probably be on them for closer to 30 mins?
My guess is the stations would need to do things (announcements etc) to get people to move their cars.